Application of the Adsorption Method for Purifying the Working Fluid in the Combined Cycle Plant Heat Recovery Loop
DOI:
https://doi.org/10.24160/1993-6982-2025-3-56-62Keywords:
adsorption, CCP, heat recovery loop, carbon sorbent, sorption capacity, ORCAbstract
The process cycle circuit of a combined-cycle power plant (CCP) with a working fluid based on fluorocarbons (C3F8) circulating in the heat recovery loop, which operates according to the organic Rankine cycle (ORC) is considered. The basic process cycle circuit and the layout diagram of the CCP with a fully sealed steam turbine casing and electrical generator are presented. The article also presents the schematic design of a unit for continuously purifying the working fluid from process impurities, elaborated on the basis of experimental data on the octafluoropropane (C3F8) sorption and desorption processes. An experimental setup for studying the sorption and desorption of fluorinated compounds is described along with the methodology for making experimental measurements. The effectiveness of octafluoropropane sorption on modified activated charcoal has been demonstrated. The mass sorption capacities of some fluorocarbon-based working substances on a modified carbon sorbent have been calculated.
References
1. Гранченко П.П., Сухих А.А., Кузнецов К.И. Термодинамический анализ применения рабочих веществ фторуглеродного состава в электрогенерирующих установках малой энергетики // Надежность и безопасность энергетики. 2017. Т. 10. № 4. С. 310—315.
2. Malyarenko V.A., Senetskyi O.V., Kolodyazhny S.V. Methodological Approach to Solving Energy Saving Issue Based on the Use of Secondary Energy Resources // Proc. Intern. Conf. Energy and Natural Sci. Lithuanian Energy Institute, 2021. Pp. 468—478.
3. Javanshir A., Sarunac N. Thermodynamic Analysis of a Simple Organic Rankine Cycle // Energy. 2017. V. 118. Pp. 85—96.
4. Shubenko O.L., Senetskyi O.V., Babak M.Yu., Sarapin V.P. Organic Rankine Cycle in the Boiler-room with Partial Use of Heat of Hot Water and Flue Gases // Znanstvena Misel J. 2018. V. 1(22). Рp. 58—64.
5. Горпинко Ю.И. и др. Двухконтурный термодинамический цикл с однонаправленным теплообменом между холодильным и энергетическим циклами // Problemele Energeticii Regionale. 2019. № 3(44). С. 51—64.
6. Кузнецов К.И. и др. Уточнённое единое уравнение состояния декафторбутана // Энергосбережение и водоподготовка. 2019. № 6(122). С. 41—44.
7. Pat. US8904791B2. Rankine Cycle Integrated with Organic Rankine Cycle and Absorption Chiller Cycle / Lehar M.A. e. a.
8. Dubinin M.M. Fundamentals of the Theory of Adsorption in Carbon Adsorbents: Characteristics of Their Adsorption Properties and Microporous Structures // Carbon. 1989. V. 27. Pp. 457—467.
9. Xue T., Cooper W.C., Pascual R. Effect of Fluoride Ions on the Corrosion of Aluminium in Sulphuric Acid and Zinc Electrolyte // J. Appl. Electrochem. 1991. V. 21. Pp. 238—246.
10. Котельникова Т.А. Адсорбционные, ионообменные и бактериостатические свойства кремнеземов, модифицированных катионами алюминия и серебра // Сорбционные и хроматографические процессы. 2018. Т. 18. № 2. С. 257—264.
11. Men’shchikov I. e. a. Carbon Adsorbents for Methane Storage: Genesis, Synthesis, Porosity, Adsorption // Korean J. Chem. Eng. 2021. V. 38. Pp. 276—291.
12. Shkolin A.V. e. a. Monolithic Microporous Carbon Absorbent for Lou Temperature Natural Gas Storage // Adsorption. 2019. V. 25(3). Pp. 1559—1573.
13. Torres-Knoop A. e. a. Behavior of the Enthalpy of Adsorption in Nanoporous Materials Close to Saturation Conditions // J. Chem. Theor. Comput. 2017. V. 13(7). Pp. 3326—3339.
14. Понуровская В.В., Ежов Е.В., Мазурин И.М., Кузнецов К.И. Экспериментальная проверка возможности сбора элегаза из камер высоковольтных аппаратов с помощью адсорбции активированным углем // Новое в российской электроэнергетике. 2024. № 2. С. 26—31.
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Для цитирования: Понуровская В.В., Кузнецов К.И., Ежов Е.В. Применение метода адсорбционной очистки рабочего тела в утилизационном контуре парогазовой установки // Вестник МЭИ. 2025. № 3. С. 56—62. DOI: 10.24160/1993-6982-2025-3-56-62
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Конфликт интересов: авторы заявляют об отсутствии конфликта интересов
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1. Granchenko P.P., Sukhikh A.A., Kuznetsov K.I. Termodinamicheskiy Analiz Primeneniya Rabochikh Veshchestv Ftoruglerodnogo Sostava v Elektrogeneriruyushchikh Ustanovkakh Maloy Energetiki. Nadezhnost' i Bezopasnost' Energetiki. 2017;10;4:310—315. (in Russian).
2. Malyarenko V.A., Senetskyi O.V., Kolodyazhny S.V. Methodological Approach to Solving Energy Saving Issue Based on the Use of Secondary Energy Resources. Proc. Intern. Conf. Energy and Natural Sci. Lithuanian Energy Institute, 2021:468—478.
3. Javanshir A., Sarunac N. Thermodynamic Analysis of a Simple Organic Rankine Cycle. Energy. 2017;118:85—96.
4. Shubenko O.L., Senetskyi O.V., Babak M.Yu., Sarapin V.P. Organic Rankine Cycle in the Boiler-room with Partial Use of Heat of Hot Water and Flue Gases. Znanstvena Misel J. 2018;1(22):58—64.
5. Gorpinko Yu.I. i dr. Dvukhkonturnyy Termodinamicheskiy Tsikl s Odnonapravlennym Teploobmenom Mezhdu Kholodil'nym i Energeticheskim Tsiklami. Problemele Energeticii Regionale. 2019;3(44):51—64. (in Russian).
6. Kuznetsov K.I. i dr. Utochnennoe Edinoe Uravnenie Sostoyaniya Dekaftorbutana. Energosberezhenie i Vodopodgotovka. 2019;6(122):41—44. (in Russian).
7. Pat. US8904791B2. Rankine Cycle Integrated with Organic Rankine Cycle and Absorption Chiller Cycle / Lehar M.A. e. a.
8. Dubinin M.M. Fundamentals of the Theory of Adsorption in Carbon Adsorbents: Characteristics of Their Adsorption Properties and Microporous Structures. Carbon. 1989;27:457—467.
9. Xue T., Cooper W.C., Pascual R. Effect of Fluoride Ions on the Corrosion of Aluminium in Sulphuric Acid and Zinc Electrolyte. J. Appl. Electrochem. 1991;21:238—246.
10. Kotel'nikova T.A. Adsorbtsionnye, Ionoobmennye i Bakteriostaticheskie Svoystva Kremnezemov, Modifitsirovannykh Kationami Alyuminiya i Serebra. Sorbtsionnye I Khromatograficheskie Protsessy. 2018;18;2:257—264. (in Russian).
11. Men’shchikov I. e. a. Carbon Adsorbents for Methane Storage: Genesis, Synthesis, Porosity, Adsorption. Korean J. Chem. Eng. 2021;38:276—291.
12. Shkolin A.V. e. a. Monolithic Microporous Carbon Absorbent for Lou Temperature Natural Gas Storage. Adsorption. 2019;25(3):1559—1573.
13. Torres-Knoop A. e. a. Behavior of the Enthalpy of Adsorption in Nanoporous Materials Close to Saturation Conditions. J. Chem. Theor. Comput. 2017;13(7):3326—3339.
14. Ponurovskaya V.V., Ezhov E.V., Mazurin I.M., Kuznetsov K.I. Eksperimental'naya Proverka Vozmozhnosti Sbora Elegaza iz Kamer Vysokovol'tnykh Apparatov s Pomoshch'yu Adsorbtsii Aktivirovannym Uglem. Novoe v Rossiyskoy Elektroenergetike. 2024;2:26—31. (in Russian)
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For citation: Ponurovskaya V.V., Kuznetsov K.I., Ezhov E.V. Application of the Adsorption Method for Purifying the Working Fluid in the Combined Cycle Plant Heat Recovery Loop. Bulletin of MPEI. 2025;3:56—62. (in Russian). DOI: 10.24160/1993-6982-2025-3-56-62
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Conflict of interests: the authors declare no conflict of interest
2. Malyarenko V.A., Senetskyi O.V., Kolodyazhny S.V. Methodological Approach to Solving Energy Saving Issue Based on the Use of Secondary Energy Resources // Proc. Intern. Conf. Energy and Natural Sci. Lithuanian Energy Institute, 2021. Pp. 468—478.
3. Javanshir A., Sarunac N. Thermodynamic Analysis of a Simple Organic Rankine Cycle // Energy. 2017. V. 118. Pp. 85—96.
4. Shubenko O.L., Senetskyi O.V., Babak M.Yu., Sarapin V.P. Organic Rankine Cycle in the Boiler-room with Partial Use of Heat of Hot Water and Flue Gases // Znanstvena Misel J. 2018. V. 1(22). Рp. 58—64.
5. Горпинко Ю.И. и др. Двухконтурный термодинамический цикл с однонаправленным теплообменом между холодильным и энергетическим циклами // Problemele Energeticii Regionale. 2019. № 3(44). С. 51—64.
6. Кузнецов К.И. и др. Уточнённое единое уравнение состояния декафторбутана // Энергосбережение и водоподготовка. 2019. № 6(122). С. 41—44.
7. Pat. US8904791B2. Rankine Cycle Integrated with Organic Rankine Cycle and Absorption Chiller Cycle / Lehar M.A. e. a.
8. Dubinin M.M. Fundamentals of the Theory of Adsorption in Carbon Adsorbents: Characteristics of Their Adsorption Properties and Microporous Structures // Carbon. 1989. V. 27. Pp. 457—467.
9. Xue T., Cooper W.C., Pascual R. Effect of Fluoride Ions on the Corrosion of Aluminium in Sulphuric Acid and Zinc Electrolyte // J. Appl. Electrochem. 1991. V. 21. Pp. 238—246.
10. Котельникова Т.А. Адсорбционные, ионообменные и бактериостатические свойства кремнеземов, модифицированных катионами алюминия и серебра // Сорбционные и хроматографические процессы. 2018. Т. 18. № 2. С. 257—264.
11. Men’shchikov I. e. a. Carbon Adsorbents for Methane Storage: Genesis, Synthesis, Porosity, Adsorption // Korean J. Chem. Eng. 2021. V. 38. Pp. 276—291.
12. Shkolin A.V. e. a. Monolithic Microporous Carbon Absorbent for Lou Temperature Natural Gas Storage // Adsorption. 2019. V. 25(3). Pp. 1559—1573.
13. Torres-Knoop A. e. a. Behavior of the Enthalpy of Adsorption in Nanoporous Materials Close to Saturation Conditions // J. Chem. Theor. Comput. 2017. V. 13(7). Pp. 3326—3339.
14. Понуровская В.В., Ежов Е.В., Мазурин И.М., Кузнецов К.И. Экспериментальная проверка возможности сбора элегаза из камер высоковольтных аппаратов с помощью адсорбции активированным углем // Новое в российской электроэнергетике. 2024. № 2. С. 26—31.
---
Для цитирования: Понуровская В.В., Кузнецов К.И., Ежов Е.В. Применение метода адсорбционной очистки рабочего тела в утилизационном контуре парогазовой установки // Вестник МЭИ. 2025. № 3. С. 56—62. DOI: 10.24160/1993-6982-2025-3-56-62
---
Конфликт интересов: авторы заявляют об отсутствии конфликта интересов
#
1. Granchenko P.P., Sukhikh A.A., Kuznetsov K.I. Termodinamicheskiy Analiz Primeneniya Rabochikh Veshchestv Ftoruglerodnogo Sostava v Elektrogeneriruyushchikh Ustanovkakh Maloy Energetiki. Nadezhnost' i Bezopasnost' Energetiki. 2017;10;4:310—315. (in Russian).
2. Malyarenko V.A., Senetskyi O.V., Kolodyazhny S.V. Methodological Approach to Solving Energy Saving Issue Based on the Use of Secondary Energy Resources. Proc. Intern. Conf. Energy and Natural Sci. Lithuanian Energy Institute, 2021:468—478.
3. Javanshir A., Sarunac N. Thermodynamic Analysis of a Simple Organic Rankine Cycle. Energy. 2017;118:85—96.
4. Shubenko O.L., Senetskyi O.V., Babak M.Yu., Sarapin V.P. Organic Rankine Cycle in the Boiler-room with Partial Use of Heat of Hot Water and Flue Gases. Znanstvena Misel J. 2018;1(22):58—64.
5. Gorpinko Yu.I. i dr. Dvukhkonturnyy Termodinamicheskiy Tsikl s Odnonapravlennym Teploobmenom Mezhdu Kholodil'nym i Energeticheskim Tsiklami. Problemele Energeticii Regionale. 2019;3(44):51—64. (in Russian).
6. Kuznetsov K.I. i dr. Utochnennoe Edinoe Uravnenie Sostoyaniya Dekaftorbutana. Energosberezhenie i Vodopodgotovka. 2019;6(122):41—44. (in Russian).
7. Pat. US8904791B2. Rankine Cycle Integrated with Organic Rankine Cycle and Absorption Chiller Cycle / Lehar M.A. e. a.
8. Dubinin M.M. Fundamentals of the Theory of Adsorption in Carbon Adsorbents: Characteristics of Their Adsorption Properties and Microporous Structures. Carbon. 1989;27:457—467.
9. Xue T., Cooper W.C., Pascual R. Effect of Fluoride Ions on the Corrosion of Aluminium in Sulphuric Acid and Zinc Electrolyte. J. Appl. Electrochem. 1991;21:238—246.
10. Kotel'nikova T.A. Adsorbtsionnye, Ionoobmennye i Bakteriostaticheskie Svoystva Kremnezemov, Modifitsirovannykh Kationami Alyuminiya i Serebra. Sorbtsionnye I Khromatograficheskie Protsessy. 2018;18;2:257—264. (in Russian).
11. Men’shchikov I. e. a. Carbon Adsorbents for Methane Storage: Genesis, Synthesis, Porosity, Adsorption. Korean J. Chem. Eng. 2021;38:276—291.
12. Shkolin A.V. e. a. Monolithic Microporous Carbon Absorbent for Lou Temperature Natural Gas Storage. Adsorption. 2019;25(3):1559—1573.
13. Torres-Knoop A. e. a. Behavior of the Enthalpy of Adsorption in Nanoporous Materials Close to Saturation Conditions. J. Chem. Theor. Comput. 2017;13(7):3326—3339.
14. Ponurovskaya V.V., Ezhov E.V., Mazurin I.M., Kuznetsov K.I. Eksperimental'naya Proverka Vozmozhnosti Sbora Elegaza iz Kamer Vysokovol'tnykh Apparatov s Pomoshch'yu Adsorbtsii Aktivirovannym Uglem. Novoe v Rossiyskoy Elektroenergetike. 2024;2:26—31. (in Russian)
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For citation: Ponurovskaya V.V., Kuznetsov K.I., Ezhov E.V. Application of the Adsorption Method for Purifying the Working Fluid in the Combined Cycle Plant Heat Recovery Loop. Bulletin of MPEI. 2025;3:56—62. (in Russian). DOI: 10.24160/1993-6982-2025-3-56-62
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Conflict of interests: the authors declare no conflict of interest
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Published
2025-02-27
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Section
Energy Systems and Complexes (2.4.5)
