Thermal Characteristics of the Waste Tire Pyrolysis Process

Authors

  • Станислав [Stanislav] Константинович [K.] Попов [Popov]
  • Вячеслав [Vyacheslav] Дмитриевич [D.] Ванюшкин [Vaniushkin]
  • Эрнест [Ernest] Акимович [A.] Сериков [Serilkov]

DOI:

https://doi.org/10.24160/1993-6982-2021-6-37-48

Keywords:

pyrolysis, material and heat balances, specific heat consumption, waste tires

Abstract

A significant annual growth in the number of spent car tires creates a serious environmental problem and calls for the need to continue searching for efficient resource-saving methods of their recycling. There is a growing number of efforts aimed at studying waste tire thermochemical conversion processes, including their pyrolysis to obtain valuable products, including a solid fraction (coke residue), liquid hydrocarbon fraction (pyrolysis oil), and noncondensable gaseous fraction (pyrolysis gas). Commercial and pilot pyrolysis plants and reactors are reviewed. A rotating drum reactor, shaft and screw reactors are the most promising solutions for implementing a continuous process.

The development of new resource-saving solutions for the pyrolysis of waste tire requires knowledge of the thermal characteristics of this process, including information on the material and heat flows in the pyrolysis reactor. The composition and thermal properties of waste tire, as well as specific outputs, composition and fuel properties of pyrolysis product material flows, including pyrolysis gas, pyrolysis oil and coke residue, are presented.

Information on the pyrolysis plant or reactor heat balance structure is either absent or incomplete. Based on the data available in the literature, the heat balance of a commercial pyrolysis plant equipped with screw reactors characterized by a specific thermal destruction heat of 0.640 MJ/(kg of tires) is drawn up and studied. The numerical analysis results correlate with the data published for the commercial-grade plant. Information on the pyrolysis chamber heat balance structure is correct enough for use in engineering practice.

It has been found that the specific heat consumption for the pyrolysis process is 2.269 MJ/(kg of tires). This value can be used in numerically analyzing pyrolysis plants equipped with other designs of pyrolysis reactors.

Author Biographies

Станислав [Stanislav] Константинович [K.] Попов [Popov]

Dr.Sci. (Techn.), Professor of Innovative Technologies for High-Tech Industries Dept., NRU MPEI, e-mail: popovsk@mpei.ru

Вячеслав [Vyacheslav] Дмитриевич [D.] Ванюшкин [Vaniushkin]

Senior Engineer of JSC «Energotsentr», e-mail: VaniushkinVD@yandex.ru

Эрнест [Ernest] Акимович [A.] Сериков [Serilkov]

Ph.D. (Techn.), Professor of Innovative Technologies for High-Tech Industries Dept., NRU MPEI, Professor of Industrial Heat Power Engineering Dept., Almaty University of Power Engineering and Telecommunications, e-mail: ernestserikov41@gmail.com

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Для цитирования: Попов С.К., Ванюшкин В.Д., Сериков Э.А. Теплотехнические характеристики процесса пиролиза отработанных шин // Вестник МЭИ. 2021. № 6. С. 37—48. DOI: 10.24160/1993-6982-2021-6-37-48
#
1. Williams P.T. Pyrolysis of Waste Tyres: A Review. Waste Management. 2013;33;8:1714—1728.
2. The Composition of a Tyre: Typical Components. Banbury: The Waste & Resources Action Programme, 2006.
3. Ramirez-Canon А. Decomposition of Used Tyre Rubber by Pyrolysis: Enhancement of the Physical Properties of the Liquid Fraction Using a Hydrogen Stream. Environments. 2018;5:72—83.
4. Kalitko V.A. Steam-thermal Recycling of Tire Shreds: Calculation of the Rate of Explosion-proof Feed of Steam. J. Engineering Phys. and Thermophys. 2008;81;4:781—786.
5. Kalitko U. Waste Tire Pyrolysis: Heat-Mass Balances & New Engineering Solutions with Steam. J. Solid Waste Techn. and Management. 2012;6:1—32.
6. Kalitko U. Triple-screw Reactor & Jet Venturi Condenser for Scrap Tire Pyrolysis Recycling with Steam [Elektron. Resurs] www.researchgate.net/publication/233965315_new_tire_pyrolysis_prospect_for_2013 (Data Obrashcheniya 08.05.2021).
7. Kalitko U. Waste Moving-Stirring Bed in Thermal Processing of Auger or Kiln Pyrolysis Reactor: Math Model Engineering Solution for the Effective Cross-Section Charge of Reactors [Elektron. Resurs] www.researchgate.net/publication/275649560 (Data Obrashcheniya 08.05.2021).
8. Castaldi M.J., Kwon E., Weiss B. Beneficial use of Waste Tires: an Integrated Gasification and Combustion Process Design via Thermogravimetric Analysis (TGA) of Styrene-Butadiene Rubber (SBR) and Polyisoprene (IR). Environmental Eng. Sci. 2007;24;8:1160—1178.
9. Naveed S., Malik A., Ramzan N., Akram M. A Comparative Study of Gasification of Food Waste (FW), Poultry Waste (PW), Municipal Solid Waste (MSW) and Used Tires (UT). Nucleus. 2009;46:77—81.
10. Kiser J.V.L. Scrap-tire Pyrolysis: The Impossible Dream?. Scrap Magazine. 2002;59;5:34—41.
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14. Kalitko U., Morgan Chun-Yao Wu. Tire Scrap Pyrolysis Recycling by Steaming Way: Heat-Mass Balance Solutions and Developments. Pyrolysis: Types, Processes, Industrial Sources and Products. N.-Y.: Nova Sci. Publ., 2009:79—115.
15. Kalitko V.A. Tire Shreds Steam-Thermal Recycling Process Modernization and Development by Inherent Gas Burning with Steam. J. Engineering Phys. and Thermophys. 2010;83;1:179—187.
16. Kalitko V.A. A Thermal-Hydrodynamic Lock Sealing with Steam Feeding for Tire Scrap Pyrolysis in Reactor of Screw Type. J. Engineering Phys. and Thermophys. 2010;83;2:324—330.
17. Kalitko U. Waste Tire Pyrolysis Recycling with Steaming: Heat-Mass Balances & Engineering Solutions for By-Products Quality. In: Material Recycling. Edited by D.S. Achilias. InTechOpen Publishers. Material Recycling —Trends and Perspectives. London: IntechOpen, 2012:213—236.
18. Williams P.T. Pyrolysis of Waste Tyres: a Review. Waste Management. 2013;33;8:1714—1728.
19. Hita I., Arabiourrutia M., Olazar M., Bilbao J., Arandes J.M., Castano P. Opportunities and Barriers for Producing High Quality Guels from the Pyrolysis of Scrap Tires. Renewable and Sustainable Energy Rev. 2016;56:745—759.
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21. GOST R 53357—2013 (ISO 17246:2010). Toplivo Tverdoe Mineral'noe. Tekhnicheskiy Analiz. (in Russian).
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23. Dinusha I. Activated Carbon from Waste Tires [Elektron. Resurs] www.researchgate.net/publication/322750723_ACTIVATED_CARBON_FROM_WASTE_TIRES?channel=doi&linkId=5a6d692f0f7e9bd4ca6c14ea&showFulltext=true (Data Obrashcheniya 08.05.2021).
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25. Geng J. Fabrication of Activated Carbon Using Two-step Co-pyrolysis of Used Rubber and Sawdust. Bioresources. 2017;12(4):8641—8652.
26. Lopez F.A., Centeno T.A., Alguacil F.J., Lobato B. Distillation of Granulated Scrap Tires in a Pilot Plant. J Hazard Mater. 2011;190:285—292.
27. Gonzalez J.F., Encinar J.M., Canito J.L., Rodrıguez J.J. Pyrolysis of Automobile Tyre Waste. Influence of Operating Variables and Kinetics Study. J. Analytical and Applied Pyrolysis. 2001;58—59:667—683.
28. Zhang W, Yin X, Wu C, Chen Y. Pyrolysis of Waste Tires in a Circulating Fluidized-bed Reactor. Energy. 2001;26:385—399.
29. Zhang X., Wang T., Chang J. Vacuum Pyrolysis of Waste Tires with Basic Additives. Waste Management. 2008;28;11:2301—2310.
30. Ucar S., Karagoz S., Ozkan A.R., Yanik J. Evaluation of Two Different Scrap Tires as Hydrocarbon Source by Pyrolysis. Fuel. 2005;84:1884—1892.
31. Ramirez-Canon А. Decomposition of Used Tyre Rubber by Pyrolysis: Enhancement of the Physical Properties of the Liquid Fraction Using a Hydrogen Stream. Environments. 2018;5(6):72—83.
32. Day M. Pyrolysis of Auto Shredder Residue: Experiments with a Laboratory Screw Kiln Reactor. J. Analytical and Applied Pyrolysis. 1999;51(1—2):181—200.
33. Barbooti M.M. Optimization of Pyrolysis Conditions of Scrap Tires under Inert Gas Atmosphere. J. Analytical and Applied Pyrolysis. 2004;72(1):165—170.
34. Galvagno S., Casu S., Casabianca T., Calabrese A., Cornacchia G. Pyrolysis Process for the Treatment of Scrap Tyres: Preliminary Experimental Results. Waste Management. 2002;22:917—923.
35. Li S.Q., Yao Q., Chi Y., Yan J.H., Cen K.F. Pilot-Scale Pyrolysis of Scrap Tires in a Continuous Rotary Kiln Reactor. Industrial Eng. Chem. Research. 2004;43;17:5133—5145.
36. Čížková A. Comparison of Yield of Tires Pyrolysis in Laboratory and Pilot Scales. GeoSci. Eng. 2009;4:60—65.
37. Kaminsky W., Mennerich C. Pyrolysis of Synthetic Rubber in a Fluidised-bed Reactor to Yield 1,3-Butadiene, Styrene and Carbon Black. J. Analytical and Appl. Pyrolysis. 2001;58—59:803—811.
38. Williams P.T., Besler S., Taylor D.T. The Pyrolysis of Scrap Automotive Tires: The Influence of Temperature and Heating Rate on Product Composition. Fuel. 1990;69:1474—1482.
39. Boxiong S., Chunfei W., Liang C., Binbin G., Rui W. Pyrolysis of Waste Tyres: the Influence of USY Catalys/Tyre Ratio on Products. J. Analytical and Appl. Pyrolysis. 2007;78:243—249.
40. Leung D.Y.C., Yin X.L., Zhao Z.L., Xu B.Y., Chen Y. Pyrolysis of Tire Powder: Influence of Operation Variables on The Composition and Yields of Gaseous Product. Fuel Processing Technology. 2002;79:141—155.
41. Kyari M., Cunliffe A., Williams P.T. Characterisation of Oils, Gases and Char in Relation to the Pyrolysis of Different Brands of Scrap Automotive Tires. Energy and Fuels. 2005;19:1165—1173.
42. Rada E.C., Ragazzi M., Dal Maschio R., Ischia M., Panaitescu V.N. Energy Recovery from Tyres Waste Through Thermal Option. Scientific Bulletin, Politehnica University of Bucharest, Series D: Mechanical Engineering. 2012; 74:201—210.
43. Williams P.T., Bottrill R.P., Cunliffe A.M. Combustion of Tyre Pyrolysis Oil. Transactions of the Institution of Chem. Engineers. 1998;76:291—301.
44. Banar M., Akyıldız V., Ozkan A., Cokaygil Z., Onay O. Characterization of Pyrolytic Oil Obtained from Pyrolysis of TDF (Tire Derived Fuel). Energy Conversion and Management. 2012;62:22—30.
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For citation: Popov S.K., Vanyushkin V.D., Serikov E.A. Thermal Characteristics of the Waste Tire Pyrolysis Process. Bulletin of MPEI. 2021;6:37—48. (in Russian). DOI: 10.24160/1993-6982-2021-6-37-48

Published

2021-05-11

Issue

Section

Industrial Power System (05.14.04)